Organic thin film transistors (TFTs) have attracted much attention due to their wide and potential applications in, e.g., flexible displays, radio frequency identification cards, and sensors. Pentacene TFTs, in which gold (Au) source/drain electrodes are commonly used as the charge-injecting metal, are particularly attractive on account of their large mobility (~ 1 cm2 V-1 s-1) and high on/off ratios (>105), particularly when compared to those for amorphous silicon TFTs. Although some promising progress has been achieved, the threshold voltage (VT) of the pentacene TFTs is still too high (~ -20 V) for practical applications. One method to reduce VT is to replace the most commonly used silicon dioxide (SiO2) substrate with a dielectric substrate having a high dielectric constant (high-κ). However, using high-κ dielectrics could decrease the charge-carrier mobility owing to the high dipolar disorder at the interface, in addition to a high leakage current and low dielectric strength. To date, reducing VT of the pentacene TFTs on SiO2 substrates is still a big challenge, especially in maintaining the high mobility.
Professor XiZhang WANG, from the Key Laboratory of Mesoscopic Chemistry, MOE of Nanjing University, and his collaborators have developed a simple and effective way to reduce VT and improve the mobility of pentacene TFTs with the commonly-used SiO2 substrate by inserting a thin metal phthalocyanine (MPc) interlayer (of only ca. 2 nm) between the Au source/drain electrodes and the pentacene active layer. In this case, VT decreased remarkably from ca. -20 V to a few volts (below -7.6 V), while the mobility increased 1.5 times after the insertion of the interlayer. The performance enhancement could be attributed to the reduction of the carrier-injection barrier between the Au source/drain electrodes and the pentacene active layer due to the involvement of the MPc interlayer. This work, entitled "Pentacene thin film transistor with low threshold voltage and high mobility by inserting a thin metal phthalocyanine interlayer", was published in SCIENCE CHINA Technological Sciences.2012, Vol 55(2). This report suggests a simple and effective way to fabricate low-threshold-voltage pentacene TFTs with high mobility on SiO2 dielectric substrates, which should be helpful for promoting their use in practical applications.
See the article: Li Y, Liu Q, Wang XZ, et al. Pentacene thin film transistor with low threshold voltage and high mobility by inserting a thin metal phthalocyanine interlayer. SCI CHINA Tech Sci, 2012, 55(2): 417
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