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PUBLIC RELEASE DATE:
22-May-2014

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Contact: Hokwang "Dave" Mao
hmao@carnegiescience.edu
Carnegie Institution
www.twitter.com/carnegiescience

Lower mantle chemistry breakthrough

Washington, D.C.óBreaking research news from a team of scientists led by Carnegie's Ho-kwang "Dave" Mao reveals that the composition of the Earth's lower mantle may be significantly different than previously thought. These results are to be published by Science.

The lower mantle comprises 55 percent of the planet by volume and extends from 670 and 2900 kilometers in depth, as defined by the so-called transition zone (top) and the core-mantle boundary (below). Pressures in the lower mantle start at 237,000 times atmospheric pressure (24 gigapascals) and reach 1.3 million times atmospheric pressure (136 gigapascals) at the core-mantle boundary.

The prevailing theory has been that the majority of the lower mantle is made up of a single ferromagnesian silicate mineral, commonly called perovskite (Mg,Fe)SiO3) defined through its chemistry and structure. It was thought that perovskite didn't change structure over the enormous range of pressures and temperatures spanning the lower mantle.

Recent experiments that simulate the conditions of the lower mantle using laser-heated diamond anvil cells, at pressures between 938,000 and 997,000 times atmospheric pressure (95 and 101 gigapascals) and temperatures between 3,500 and 3,860 degrees Fahrenheit (2,200 and 2,400 Kelvin), now reveal that iron bearing perovskite is, in fact, unstable in the lower mantle.

The team finds that the mineral disassociates into two phases one a magnesium silicate perovskite missing iron, which is represented by the Fe portion of the chemical formula, and a new mineral, that is iron-rich and hexagonal in structure, called the H-phase. Experiments confirm that this iron-rich H-phase is more stable than iron bearing perovskite, much to everyone's surprise. This means it is likely a prevalent and previously unknown species in the lower mantle. This may change our understanding of the deep Earth.

"We still don't fully understand the chemistry of the H-phase," said lead author Li Zhang, also of Carnegie. "But this finding indicates that all geodynamic models need to be reconsidered to take the H-phase into account. And there could be even more unidentified phases down there in the lower mantle as well, waiting to be identified."

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The research is supported by National Science Foundation (NSF) grants EAR-0911492, EAR-1119504, EAR-1141929, and EAR-1345112. This work was performed at HPCAT (Sector 16), Advanced Photon Source (APS), Argonne National Laboratory. HPCAT operations are supported by the U.S. Department of Energy-Basic Energy Sciences-National Nuclear Security Administration (DOE-NNSA) under Award DE-NA0001974 and DOE-Basic Energy Sciences (BES) under Award DE-FG02-99ER45775, with partial instrumentation funding by NSF. HPSynC is supported as part of EFree, an Energy Frontier Research Center funded by DOE-BES under grant DE-SC0001057. Portions of this work were performed at GeoSoilEnviroCARS (sector 13), APS, supported by the NSF-Earth Sciences (EAR-1128799) and DOE-GeoSciences (DE-FG02-94ER14466), at 34ID-E beamline, APS, and at 15U1, Shanghai Synchrotron Radiation Facility. Use of the APS facility was supported by DOE- BES under contract DE-AC02-06CH11357. This work was also partially supported by the Materials Research and Engineering Center program of the NSF under award DMR-0819885. Part of this work was carried out in the Characterization Facility of the University of Minnesota.

The Carnegie Institution for Science is a private, nonprofit organization headquartered in Washington, D.C., with six research departments throughout the U.S. Since its founding in 1902, the Carnegie Institution has been a pioneering force in basic scientific research. Carnegie scientists are leaders in plant biology, developmental biology, astronomy, materials science, global ecology, and Earth and planetary science.



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