Figure Abstract (IMAGE)
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Both Pd single atoms (Pd1) and clusters (Pdc) were constructed in three-dimensional ordered macroporous (3DOM) In2O3 for photocatalytic CO2 reduction with H2O. The large surface area and abundant pore channels of 3DOM-In2O3 facilitate mass transfer and intermediate enrichment. The synergisticPd1 and Pdc active sites enhance the adsorption and activation of CO2 and H2O. The localized surface plasmon resonance of Pd clusters induces a photothermal effect, further accelerating the reaction kinetics.
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Chinese Journal of Catalysis
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