Cross-scale Raman thermometry: Bridging equilibrium-to-non-equilibrium thermal dynamics from micro-devices to single-molecule junctions (IMAGE)
Caption
This graphical summary illustrates the comprehensive framework for cross-scale Raman thermometry, which bridges the gap between macroscopic thermal management and molecular-level energy dynamics. The progression moves from far-field Micro-Raman imaging of semiconductor hotspots (~1 µm) to near-field Tip-Enhanced Raman Spectroscopy (TERS) capable of probing single-molecule junctions (~1 nm). The framework highlights the transition from classical thermal equilibrium to non-equilibrium states governed by quantum fluctuations where traditional definitions of temperature no longer apply. The lower section depicts the integration of AI-driven spectral analysis and databases, envisioning an automated ecosystem for the intelligent thermal design of next-generation nano-electronics
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Nano Research, Tsinghua University Press
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