Octahedral Cage of the Catalyst (IMAGE)
Caption
Four resorcinol molecules are linked to form a large ring consisting of 16 carbon atoms. Six of these molecules self-assemble in solution to an octahedron-like cage. The electron-rich aromatic ring systems of the resorcinol-blocks appear to stabilize the positive charge of the intermediate state. Similar to the reaction pocket of the cyclase enzyme of the eucalyptus tree, the catalyst thus prevents undesirable side reactions.
Credit
Image: Johannes Richers / TUM
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