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(a) Schematic presentation of the 'Orbital Electrostatic Energy (OEE)'. The binding energies (BE) of the BF4--π complexes plotted versus (b) the extrema of the electrostatic potential surface above the center of the arene ring with molecular electron density being rendered at the 0.001 a.u. (ESPext) and (c) the orbital electrostatic energy (OEE).
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