"Rocks, fossils, and other natural relics hold clues to ancient environments in the form of different ratios of isotopes--atomic variants of elements with the same number of protons but different numbers of neutrons," explained Rumble. "Seawater, rain water, oxygen, and ozone, for instance, all have different ratios, or fingerprints, of the oxygen isotopes 16O, 17O, and 18O. Weathering, ground water, and direct deposition of atmospheric aerosols change the ratios of the isotopes in a rock revealing a lot about the past climate." Rumble's paper describes how geochemists, mineralogists, and petrologists are studying anomalies of isotopes of oxygen and sulfur to piece together what happened to our atmosphere from about 3.9 billion years ago, when the crust of our planet was just forming and there was no oxygen in the atmosphere, to a primitive oxygenated world 2.3 billion years ago, and then to the present.
The detective work involves a pantheon of scientists who have analyzed surface minerals from all over the globe, used rockets and balloons to sample the stratosphere, collected and studied ice cores from Antarctica, conducted lab experiments, and run mathematical models. The synthesis from the different fields and techniques points to ultraviolet (UV) light from the Sun as an important driving force in atmospheric evolution. Solar UV photons break up molecular oxygen (O2) to produced ozone (O3) leaving a tell-tale isotopic signature of excess 17O. The ozone layer began to form as the atmosphere gained oxygen, and has since shielded our planet from harmful solar rays and made life possible on Earth's surface.
The discovery of isotope anomalies, where none were previously suspected, adds a new tool to research on the relationships between shifts in atmospheric chemistry and climate change. Detailed studies of polar-ice cores and exposed deposits in Antarctic dry valleys may improve our understanding of the history of the ozone hole.