Public Release: 

Reverse combustion? Turning carbon dioxide from burning fossil fuel back into fuel

American Chemical Society

INDIANAPOLIS, Sept. 8, 2013 -- With almost 40 billion tons of carbon dioxide (CO2) released each year from burning coal, gasoline, diesel and other fossil fuels in the United States alone, scientists are seeking ways to turn the tables on the No. 1 greenhouse gas and convert that troublesome CO2 back into fuel.

Those efforts to unring one of the bells of global warming are the topic of a symposium here today at the 246th National Meeting & Exposition of the American Chemical Society, the world's largest scientific society. Thousands of scientists and others are expected for the meeting, which features almost 7,000 reports on new discoveries in science and other topics and continues through Thursday in the Indiana Convention Center and downtown hotels.

Converting CO2 into a renewable energy sources would involve capturing the gas from the smokestacks of coal-fired electric power generating stations, for instance, and processing it with catalysts or other technology into fuels and raw materials for plastics and other products.

Abstracts in the symposium appear below.


A press conference on this topic is tentatively scheduled for Sunday, Sept. 8, at 3 p.m. in the ACS Press Center, Room 211, in the Indiana Convention Center. Reporters can attend in person or access live audio and video of the event and ask questions at

The American Chemical Society is a nonprofit organization chartered by the U.S. Congress. With more than 163,000 members, ACS is the world's largest scientific society and a global leader in providing access to chemistry-related research through its multiple databases, peer-reviewed journals and scientific conferences. Its main offices are in Washington, D.C., and Columbus, Ohio.

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Homogeneous reduction of formic acid by pyridine: A key step in CO2 reduction to CH3OH

Chern-Hooi Lim1,, Aaron M. Holder1,2, Charles B. Musgrave1,2. (1) Department of Chemical and Biological Engineering, University of Colorado at Boulder, Boulder, Colorado 80309-0596, United States, (2) Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, Colorado 80309-0596, United States

One key obstacle in CO2 reduction that is often overlooked is the reduction of formic acid (HCOOH), a common intermediate en route to CH3OH production. In fact, most CO2 reduction catalysts successfully convert CO2 to HCOOH or its deprotonated form formate (HCOO-), but fail to achieve the subsequent reduction of HCOOH to ultimately produce CH3OH. We address this challenge by showing how competent catalysts, when synergistically combined with optimum reaction conditions, can accomplish HCOOH reduction. We employ high-level CCSD(T) quantum chemical calculations to demonstrate a viable concerted proton-coupled electron transfer (PCET) mechanism for the homogeneous reduction of formic acid (HCOOH) by pyridinium radical (PyH0) and hydronium ion (H3O+). The predicted barrier (∆H0act) for concerted PCET to convert HCOOH to PyH+•CH(OH)20 is 10.5 kcal/mol. PyH+•CH(OH)20 can then dissociate and complex with pyridine to form Py•CH(OH)20, which undergoes condensation and ultimately forms Py•OCH0, a proposed intermediate in formaldehyde formation. The highest barrier step for HCOOH reduction is the condensation reaction which results in C-O bond cleavage with ∆H0act = 14.9 kcal/mol. The electron affinity and pKaquantitatively show that concerted PCET is favored over sequential PCET in the PyH0 catalyzed reduction of HCOOH due to the high cost of localizing electron density on HCOOH and deprotonating PyH0.

CO2 chemistry: Catalytic transformation of carbon dioxide based on its activation

Liang-Nian He,, Zhen-Zhen Yang, An-Hua Liu, Bing Yu, Yu-Nong Li. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, China

Carbon dioxide chemistry (in particular, capture and conversion) has attracted much attention from the scientific community due to global warming associated with positive carbon accumulation.1-2 in this context, CO2 is very attractive as an environmentally friendly feedstock for making commodity chemicals, fuels, and materials from a standpoint of C1 chemistry and green chemistry. The challenge is to develop catalysts that are capable of activating CO2 under low pressure (preferably at 1 atm), and thus incorporating CO2 into organic molecules catalytically. 3-5 CO2 could be activated through the formation of carbamate/alkyl carbonate with Lewis basic nitrogen species. In this work, we would like to discuss and update advances on C-N bond formation with the production of oxazolidinones, quinazolines, carbamates, isocyanates and polyurethanes using CO2 as C1 feedstock, and CO2 capture by amino-functionalized ionic liquids presumably leading to CO2's activation and thus subsequent conversion through C-N bond formation pathway.

Molecular catalysts for the reduction of CO2 to CO or formate

Aaron M Appel,, John C Linehan, Brian J Boro, Brandon R Galan, Matthew S Jeletic, Sonja M Peterson. Pacific Northwest National Laboratory, Richland, WA 99353, United States

The efficient reduction of CO2 requires the development of new catalysts for the interconversion of this substrate and the corresponding fuels. Inspiration from nature can provide a starting point for the design of catalysts through the incorporation of bifunctional interactions. The latest results from our lab will be presented for the catalytic reduction of CO2 using molecular complexes for both hydrogenation and electrocatalytic reduction, as well as related transformations, with a focus on balancing reaction energetics. For the electrocatalytic reduction of CO2, the emphasis will be on analogs of previously reported palladium triphosphine complexes, and for the hydrogenation of CO2, our efforts in using complexes of first row transition metals will be presented.

Catalytic activation of CO2 over lanthanum zirconate (La2Zr2O7) pyrochlores and its role in dry (CO2) reforming of CH4

Devendra Pakhare1,, Viviane Schwartz2, Victor Abdelsayed3, Daniel Haynes3, Dushyant Shekhawat3, James Spivey1. (1) Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States, (2) Oak Ridge National Laboratory, Oak Ridge, TN 37831, United States, (3) National Energy Technology Laboratory, Morgantown, WV 26507, United States

Dry reforming of methane (DRM) is an endothermic reaction and the catalysts used for studying this reaction are unsubstituted lanthanum zirconate (LZ), Rh substituted LRhZ (2 wt%) and LRhZ (5 wt%) pyrochlores. In-situ FTIR studies in CO2 and CH4 were conducted on these three catalysts. The FTIR spectra obtained were then analyzed for the formation of carbonates and formates during DRM reaction. Lanthanum oxide (La2O3) and zirconium oxide (ZrO2) were used as standards for analyzing the carbonate formation over the pyrochlores. It was observed that the absorption spectra of the lanthanum oxide carbonates were very similar to carbonates formed on LZ. There were no observable carbonates formed on zirconia. This suggests that the active site for activation of CO2 is the lanthanum phase of LZ. Lanthanum oxide forms carbonate which then oxidize activated CH4 during the DRM reaction.

Electrocatalytic reduction of CO2 to CO by monodisperse Au nanoparticles

Wenlei Zhu,, Onder Metin, Chritopher Wright, Shouheng Sun. Department of chemistry, brown university, providence, RI 02912, United States

Converting CO2 to active carbon forms, such as CO, formic acid, methanol and other hydrocarbons is considered an essential approach to sustainable use of fuels/chemicals. Recent studies have centered on CO2 capture, secure storage, and chemical conversions. Among various chemical reactions studied, electrochemical reduction is considered a potentially efficient way to convert CO2 selectively into CO or other hydrocarbon fuels over metal electrodes. Among all metals tested for the electrochemical reduction of CO2, gold is the most attractive one for its catalytic reduction of CO2 to CO. Herein, we present the electrochemical reduction of CO2 to CO with high Faradic efficiency by monodisperse Au nanoparticles. The reduction reaction was tested in aqueous solution of potassium bicarbonate. The working electrode was prepared by the deposition of carbon supported Au NPs over the carbon paper via polyvinylidene fluoride. The electrocatalysis was performed at different potentials (-0.3 V to -0.9 V vs. RHE) and the reduction was found to be Au NP size dependent. With all Au NPs tested, only CO was detected as the gas product while a very low amount of formic acid was found in the liquid phase product analysis. The highest Faradic efficiency of 90% was calculated for the 8 nm Au NPs catalyst at -0.6 V. Our studies show that Au NPs when properly synthesized and activated are selective for electrochemical reduction of CO2 to CO.

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