BOSTON, Aug. 16, 2015 -- Sunlight can be brutal. It wears down even the strongest structures, including rooftops and naval ships, and it heats up metal slides and bleachers until they're too hot to use. To fend off damage and heat from the sun's harsh rays, scientists have developed a new, environmentally friendly paint out of glass that bounces sunlight off metal surfaces -- keeping them cool and durable.
The researchers present their work today at the 250th National Meeting & Exposition of the American Chemical Society (ACS). ACS, the world's largest scientific society, is holding the meeting here through Thursday. It features more than 9,000 presentations on a wide range of science topics. A brand-new video on the research is available at http://bit.ly/acscoatings.
"Most paints you use on your car or house are based on polymers, which degrade in the ultraviolet light rays of the sun," says Jason J. Benkoski, Ph.D. "So over time you'll have chalking and yellowing. Polymers also tend to give off volatile organic compounds, which can harm the environment. That's why I wanted to move away from traditional polymer coatings to inorganic glass ones."
Glass, which is made out of silica, would be an ideal coating. It's hard, durable and has the right optical properties. But it's very brittle.
To address that aspect in a new coating, Benkoski, who is at the Johns Hopkins University Applied Physics Lab, started with silica, one of the most abundant materials in the earth's crust. He modified one version of it, potassium silicate, that normally dissolves in water. His tweaks transformed the compound so that when it's sprayed onto a surface and dries, it becomes water resistant.
Unlike acrylic, polyurethane or epoxy paints, Benkoski's paint is almost completely inorganic, which should make it last far longer than its counterparts that contain organic compounds. His paint is also designed to expand and contract with metal surfaces to prevent cracking.
Mixing pigments with the silicate gives the coating an additional property: the ability to reflect all sunlight and passively radiate heat. Since it doesn't absorb sunlight, any surface coated with the paint will remain at air temperature, or even slightly cooler. That's key to protecting structures from the sun.
"When you raise the temperature of any material, any device, it almost always by definition ages much more quickly than it normally would," Benkoski says. "It's not uncommon for aluminum in direct sunlight to heat 70 degrees Fahrenheit above ambient temperature. If you make a paint that can keep an outdoor surface close to air temperature, then you can slow down corrosion and other types of degradation."
In fact, the paint Benkoski's lab is developing is intended for use on naval ships. But it has many other potential commercial applications.
"You might want to paint something like this on your roof to keep heat out and lower your air conditioning bill in the summer," he says. It could even go on metal playground slides or bleachers. And it would be affordable. The materials needed to make the coating are abundant and inexpensive.
Benkoski says he expects his lab will start field testing the material in about two years.
A press conference on this topic will be held Monday, Aug. 17, at 10 a.m. Eastern time in the Boston Convention & Exhibition Center. Reporters may check-in at Room 153B in person, or watch live on YouTube http://bit.ly/ACSLiveBoston. To ask questions online, sign in with a Google account.
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He acknowledges funding from the U.S. Office of Naval Research.
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Title
Passive cooling with UV-resistant siloxane coatings in direct sunlight
Abstract
Solar exposure is a leading cause of material degradation in outdoor use. Polymers and other organic materials photo-oxidize due to ultraviolet (UV) exposure. Even in metals, solar heating can cause unwanted property changes through precipitation and Ostwald ripening. In more complex systems, cyclic temperature changes cause fatigue failure wherever thermal expansion mismatch occurs. Most protective coatings designed to prevent these effects inevitably succumb to the same phenomena because of their polymeric matrix. In contrast, siloxane coatings have the potential provide indefinite solar protection because they do not undergo photo-oxidation. This study therefore demonstrates UV-reflective siloxane coatings with low solar absorptance and high thermal emissivity that prevent any increase in temperature above ambient conditions in direct sunlight. Mathematical modeling suggests that even sub-ambient cooling is possible for ZnO-filled potassium silicate. Preventing widespread adoption of potassium silicates until now has been their tendency to crack at large thicknesses, dissolve in water, and delaminate from untreated surfaces. This investigation has successfully addressed these limitations by formulating potassium silicates to behave more like a flexible siloxane polymer than a brittle inorganic glass. The addition of plasticizers (potassium, glycerol), gelling agents (polyethylenimine), and water-insoluble precipitates (zinc silicates, cerium silicates, organosilanes) make it possible to form thick, water resistant coatings that exhibit excellent adhesion even to untreated aluminum surfaces.