A research team from the Faculty of Physics of Lomonosov Moscow State University found out a stretching of acicular diamond crystallites under action of an electric field. Deformation occurring during the stretching causes changes in luminescence spectrum. This effect can be used for development electric field detectors and other quantum optic devices. The work was published in Nano Letters magazine.
Diamonds are minerals composed of carbon and widely known by their phenomenal hardness. Besides diamonds possess other outstanding features. Similar to other crystals, diamonds always contain structural defects. Some of them cause changes in coloring (light absorption) or luminescence and are called color centers. Specific characteristics some types of the color centers in diamonds make them suitable for use in quantum optic devices such as qubits that are based on entanglement of the photons quantum states. For a diamond to be used in such devices, the distance between its individual color centers should be about 30 nm.
A research team headed by Alexander Obraztsov, professor of the Department of Polymer and Crystal Physics of the Faculty of Physics, MSU has found out a method of mass production of diamond micro-needles in its previous studies. This method includes, at first, growth of diamond crystallites as a fraction of the films (containing also other non-diamond fractions) formed by chemical vapor deposition of methane and hydrogen mixture. After that all spare materials are removed (by burning) from the films by means of their heating in the air.
"In this new work we tried to learn as much as possible about diamond needles that we produce, specifically about their color centers," said professor Obraztsov. In order to understand the location of color centers in the structure of the samples and to find out their properties, Russian scientists turned to their French colleagues that use a unique methodology for the required analysis. "Our French colleagues apply it to study chemical composition and location of impurities in different materials," explained Obraztsov.
During the measurements diamond needles were attached to an electrode placed into a high vacuum chamber. To achieve the stretching effect, high voltage was applied to the electrode causing electrical polarization of the dielectric diamond, as well as considerable mechanical stress stretching the needle. The stretching caused deformation of diamond's crystal structure.
According to the authors, this leads to changes in individual color centers as well, and their quantum optic properties alter together with the structure. Before that scientists were only able to compress diamonds, and this is the first time ever a diamond has been stretched.
During sample stretching it was irradiated with a laser and luminescence of the color centers was registered with a spectrometer. The experiment showed changes of shape and energy of the luminescence bands depending on the stretching force determined by the applied voltage. The team believes that similar diamond needles could be used to create detectors for contact-free measuring of electric fields with high spatial resolution.
"Detectors like this could be used not only to measure the fields created by high voltage in high vacuum, but those existing in biological molecules (DNA, RNA, etc.). Measurement of such fields is a burning scientific issue today," commented Obraztsov. The dimensions of diamond needles at their apex are of several to several hundred nanometers. Therefore, according to the scientists, measurements could be made with precision that corresponds to certain molecule fragments.
Diamond micro-needles produced with the use of the method developed by the MSU team would also be able to secure contact-free optical detection of magnetic fields, temperature, and other characteristics with nano- and microscopic spatial resolution.