A new paper published today in Nature Energy reveals how a collaborative team of researchers have been able to fully identify the nature of oxidised oxygen in the important battery material - Li-rich NMC - using RIXS (Resonant Inelastic X-ray Scattering) at Diamond Light Source. This compound is being closely considered for implementation in next generation Li-ion batteries because it can deliver a higher energy density than the current state-of-the-art materials, which could translate to longer driving ranges for electric vehicles. They expect that their work will enable scientists to tackle issues like battery longevity and voltage fade with Li-rich materials.
The paper, "First cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk" by a joint team from the University of Oxford, the Henry Royce and Faraday Institutions and Diamond Light Source, the UK's national synchrotron examines the results of their investigations to better understand the important compound known in the battery industry as Li-rich NMC (or Li1.2Ni0.13Co0.13Mn0.54O2).
Principal Beamline Scientist on I21 RIXS at Diamond, Kejin Zhou, explains: "Our work is much about understanding the mysterious first cycle voltage hysteresis in which the O-redox process cannot be fully recovered resulting in the loss of the voltage hence the energy density."
A previous study (Nature 577, 502-508 (2020)) into this process made by the same research team, at the I21 beamline at Diamond, reported that, in Na-ion battery cathodes, the voltage hysteresis is related to the formation of molecular O2 trapped inside of the particles due to the migration of transition metal ions during the charging process.
He adds: "Our current work, focuses on the Li-rich material Li1.2Ni0.13Co0.13Mn0.54O2. The key findings as before show the formation of free O2 molecules inside the materials, which has not been appreciated before in the community. This is a very important discovery as the material has higher TM-O covalency which was thought to suppress formation of molecular O2. I believe our work will have huge impact in future battery cathodes designs to minimise the unstable honeycomb structure. Our work also has important consequences for tackling other issues associated with Li-rich NMC, such as voltage fade, which hinder their commercialisation and ultimately discovering new materials which may be able to harness O-redox more reversibly."
Li-rich cathode materials are one of the very few options available to increase the energy density of Li-ion batteries. Almost all of the lithium in these structures can be removed, compensated first by oxidation of the transition metal (TM) ions and subsequently the oxide ions. However, the high voltage associated with this O-redox process on charge is not recovered on discharge leading to so called voltage hysteresis and a substantial loss of energy density. This represents one of the key challenges that has inhibited exploiting the full potential of these materials and the understanding of this phenomenon remains incomplete.
"In our study, we used HR RIXS - High Resolution- Resonant Inelastic X-ray Scattering spectroscopy at beamline I21 at Diamond to investigate the O-redox process. This is how the material stores charge on the oxide ions, which make up part of its structure. However, this process has proved very difficult for researchers to understand fully. The material undergoes complicated structural changes during the first charge resulting in large voltage hysteresis, and the mechanism by which oxide ions store energy was unclear," explains lead author, Dr Rob House, University of Oxford, Department of Materials. He also adds:
"The data we achieved allowed us to assign mysterious spectroscopic features that had previously been detected by the RIXS technique , but could not be fully identified. We were able to resolve fine structure arising from the vibrations of O2 molecules allowing us to assign the RIXS features obtained in this important class of battery material. These O2 molecules are trapped within the bulk of the cathode material and can be reformed back into oxide ions during discharge, but at a lower voltage than on the initial charge. This provides a new mechanism for explaining the O-redox process and represents an important step forward for battery materials."
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"First cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk." The DOI number for this paper is 10.1038/s41560-020-00697-2. Once published online, it will be available at the following URL: https:/
Authors: Robert A. House1,2,3,4, Gregory J. Rees1,2,3,4, Miguel A. Pérez-Osorio1,2,3,4, John-Joseph Marie1,2,3,4, Edouard Boivin1,2,3, Alex W. Robertson1,2,3, Abhishek Nag5, Mirian Garcia-Fernandez5, Ke-Jin Zhou5 and Peter G. Bruce1,2,3,4,*
1. Department of Materials, University of Oxford, Parks Road, Oxford, OX3 1PH, U.K. 2. Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QZ, U.K. 3. The Henry Royce Institute, Parks Road, Oxford, OX1 3PH, U.K. 4. The Faraday Institution, Quad One, Becquerel Avenue, Harwell Campus, Didcot, OX11 0RA, U.K. 5. Diamond Light Source, Harwell, U.K.
Li-rich cathode materials are potential candidates for next generation Li-ion batteries. However, they exhibit large voltage hysteresis on the 1st charge/discharge cycle involving a substantial (up to 1V) loss of voltage and therefore energy density. For Na cathodes, e.g. Na0.75[Li0.25Mn0.75]O2, voltage hysteresis can be explained by formation of molecular O2 trapped in voids within the particles. Here we show that this is also the case for Li1.2Ni0.13Co0.13Mn0.54O2. RIXS and 17O MAS NMR show that molecular O2, rather than O22-, forms within the particles on oxidation of O2- at 4.6 V vs Li+/Li on charge. These O2 molecules are reduced back to O2- on discharge but at the lower voltage of 3.75 V explaining the voltage hysteresis in Li-rich cathodes. 17O MAS NMR indicates a quantity of bulk O2 consistent with the O-redox charge capacity minus the small quantity of O2 loss from the surface. The implication is that O2, trapped in the bulk and lost from the surface, can explain O-redox.
Li-rich cathode materials, such as Li1.2Ni0.13Co0.13Mn0.54O2 where Li:TM>1, are one of the very few options available to increase the energy density of Li-ion batteries.1-3 Almost all of the lithium in these structures can be removed, compensated first by oxidation of the transition metal (TM) ions and subsequently the oxide ions, the latter at a constant potential of 4.6 V vs Li+/Li.4-10 However, the high voltage associated with this O-redox process on charge is not recovered on discharge leading to so called voltage hysteresis and a substantial loss of energy density. This represents one of the key challenges that has inhibited exploiting the full potential of these materials and the understanding of this phenomenon remains incomplete.
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