Change in Electronic State (IMAGE)

Tohoku University

Change in Electronic State

Caption

These are schematic depictions of the Jahn-Teller molecular distortion of the fullerene units in the Mott-Jahn-Teller insulator (blue molecules) and the Jahn-Teller metal (yellow molecules), their respective molecular electronic structure (lifting of the orbital degeneracy due to the distortion), and the resulting intermolecular hopping of the electrons (prohibited in the insulator, weak hopping in the Jahn-Teller metal). This situation contrasts with the behavior of the conventional metal where hopping is allowed, the orbital degeneracy is retained, and the molecules are undistorted (green molecules).

Credit

Prassides Kosmas

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Credit: Prassides Kosmas

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