Catalyzing Nitrobenzene into Aniline Using Safe Hydrogenation (IMAGE)
Caption
UJ researchers used Pickering emulsions to show that hydrogenation can be much safer. In a novel catalyzed process, the toxic waste product nitrobenzene is turned into aniline. Aniline is a valuable feedstock in the chemical and pharmaceutical industries. The three-phase catalyzed process is efficient at room temperature.
This study is the first efficient application of a bimetalic palladium catalyst for the hydrogenation of an aromatic compound in a water-based Pickering emulsion system.
Above are the Transmission Electron Microscope (TEM) images of (a) Silica microspheres, (b) Methyl modified silica microspheres, (c) bifunctionalized modified silica microspheres, (d) Pd/SM-CN, (e) PdCo/SMCN, (f) PdNi/SM-CN.
Chemists from the University of Johannesburg have demonstrated this, in research published in Colloids and Surfaces at https://www.sciencedirect.com/science/article/abs/pii/S0927775721003824
Credit
Transmission Electron Microscope (TEM) images by Dele Peter Fapojuwo, University of Johannesburg. Graphic design by Therese van Wyk, University of Johannesburg.
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