IR Spectra of CH<sub>2</sub>Cl<sub>2</sub>-Inserted V12 and Guest-Free V12 (IMAGE)

Kanazawa University

IR Spectra of CH<sub>2</sub>Cl<sub>2</sub>-Inserted V12 and Guest-Free V12

Caption

IR spectra of CH2Cl2-inserted V12 and guest-free V12 are shown in black and red spectra, respectively. The peak position in the highlighted region of guest-inserted V12 and guest-free V12 is different due to the VO5 unit inversion. The spectra of guest-free V12 are recorded under atmospheric pressure of CO2 (blue) and CO (green) at 25 ºC. From the peak position, CO2 can be interacted with the V12 bowl inside, while CO show no interaction with the bowl inside.

Credit

Kanazawa University

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