News Release

Investigation of degradation mechanism for all-solid-state batteries takes another step toward commercialization

New findings reveal how degradation of all-solid-state batteries occurs at the cathode under low-pressure operation. Clues to accelerate commercialization of all-solid-state batteries.

Peer-Reviewed Publication

National Research Council of Science & Technology

Figure 1


Comparison of cathode volume changes in all-solid-state cells under low-pressure operated

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Credit: Korea Institute of Science and Technology

Often referred to as the ‘dream batteries’, all-solid-state batteries are the next generation of batteries that many battery manufacturers are competing to bring to market. Unlike lithium-ion batteries, which use a liquid electrolyte, all components, including the electrolyte, anode, and cathode, are solid, reducing the risk of explosion, and are in high demand in markets ranging from automobiles to energy storage systems (ESS). However, devices that maintain the high pressure (tens of MPa) required for stable operation of all-solid-state batteries have problems that reduce the battery performance, such as energy density and capacity, and must be solved for commercialization.

Dr. Hun-Gi Jung and his team at the Energy Storage Research Center at the Korea Institute of Science and Technology (KIST) have newly identified degradation factors that cause rapid capacity degradation and shortened lifespan when operating all-solid-state batteries at pressures similar to those of lithium-ion batteries. Unlike previous studies, the researchers confirmed for the first time that degradation can occur inside the cathode as well as outside, showing that all-solid-state batteries can be operated reliably even in low-pressure environments in the future.

In all-solid-state batteries, the cathode and anode have a volume change during repeated charging and discharging, resulting in interfacial degradation such as side reaction and contact loss between active materials and solid electrolytes, which increase the interfacial resistance and worsen cell performance. To solve this problem, external devices are used to maintain high pressure, but this has the disadvantage of reducing energy density as the weight and volume of the battery increase. Recently, research is being conducted on the inside of the all-solid-state cell to maintain the performance of the cell even in low-pressure environments.

The research team analyzed the cause of performance degradation by repeatedly operating a coin-type all-solid-state battery with a sulfide-based solid electrolyte in a low-pressure environment of 0.3 MPa, similar to that of a coin-type Li-ion battery. After 50 charge-discharge cycles, the NCM cathode layer had expanded in volume by about two times, and cross-sectional image analysis confirmed that severe cracks had developed between the cathode active material and the solid electrolyte. This newly revealed that in addition to the interfacial contact loss, cracking of the cathode material and irreversible cathode phase transformation are the causes of degradation in low-pressure operation.

Furthermore, after replacing the lithium in the cathode with an isotope (6Li) to distinguish it from the lithium present in the solid electrolyte, the team used time-of-flight secondary ion mass spectrometry (TOF-SIMS) to identify for the first time the mechanism by which lithium consumption in the cathode contributes to the overall cell capacity reduction. During repeated charge-discharge cycles, sulfur, a decomposed product of the solid electrolyte, infused the cracks in the cathode material to form lithium sulfide, a byproduct that is non-conductive. This depleted the active lithium ions and promoted cathode phase transformation, reducing the capacity of the all-solid-state batteries.

By clearly identifying the cause of the degradation of all-solid-state batteries in low-pressure operating environments, these analytical methods provide a clue to solving the problem of poor cycling characteristics compared to conventional lithium-ion batteries. If this problem is solved, it is expected that the economics of all-solid-state batteries can be secured by eliminating external auxiliary devices, which have been a major cause of rising production costs.

"For the commercialization of all-solid-state batteries, it is essential to develop new cathode and anode materials that can be operated in a pressure-free or low-pressure environment rather than the current pressurized environment," said Dr. Hun-Gi Jung of KIST. "When applying low-pressure-working all-solid-state batteries to medium and large-scale applications such as electric vehicles, it will be expected to make full use of established lithium-ion battery manufacturing facilities."


KIST was established in 1966 as the first government-funded research institute in Korea. KIST now strives to solve national and social challenges and secure growth engines through leading and innovative research. For more information, please visit KIST’s website at

This research was supported by the Korea Institute of Science and Technology institutional program funded by the Ministry of Science and ICT of Korea (Minister Lee Jong-ho), by the Development Program of Core Industrial Technology funded by the Ministry of Trade, Industry and Energy (Minister Bang, Moon Kyu), and by the Technology Development Program to Solve Climate Changes funded by the National Research Foundation (President Lee, Kwang-bok). The research results were published as a front cover article in the latest issue of Advanced Energy Materials (IF 27.8, top 2.5% in JCR), an international journal in the field of energy materials.

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