image: Managing the level of magnesium impurity purification emerges as a pivotal process in regulating secondary battery cathode material productivity, longevity, and eco-friendliness.
Credit: POSTECH
Manufacturers of secondary battery cells (LG Energy Solution, Samsung SDI, and SK on) have been insisting on very stringent purity specifications from suppliers of cathode materials to ensure a consistent quality output. The purity specifications for cathode materials have been closely guarded as trade secrets with little active scrutiny on the necessity of such high specifications. In response to the demands of cell manufacturers, suppliers of cathode materials have been investing significantly in purifying raw metals, consequently raising the unit cost of batteries.
A research team led by Professor Yong-Tae Kim from the Department of Materials Science and Engineering at Pohang University of Science and Technology (POSTECH), in collaboration with Professor Kyu-Young Park from the Graduate Institute of Ferrous & Eco Materials Technology and the Department of Materials Science and Engineering at POSTECH, and the research team of Dr. Woochul Jung from the Research Institute of Industrial Science and Technology (RIST), has discovered that the purity specifications for cathode materials, as set by cell manufacturers, are overly stringent. Their research demonstrates that streamlining the lithium refining process could substantially reduce the unit cost of batteries. The research findings are published in ‘Nature Communications’, one of international scientific journals.
In this research, the team delved into the impact of lithium raw material purity on the production and performance of secondary battery cathode materials. Conventionally, it's assumed that impurities in lithium materials hamper secondary battery performance. Therefore, the goal is to manufacture lithium materials with purity of at least 99.5%. Nevertheless, the team uncovered that the presence of approximately 1% magnesium (Mg) impurity in the lithium raw material actually enhances process efficiency and prolongs the secondary battery's lifespan. Through their experiments, they demonstrated that utilizing low-purity lithium, not entirely rid of impurities, could reduce secondary battery production costs and carbon dioxide emissions by up to 19.4% and 9.0%, respectively.
Professor Yong-Tae Kim who led the research stated, " Secondary battery cell manufacturers need to reassess whether their current cathode material specifications are too stringent." He further remarked, “Considering unconventional approaches could offer a fresh strategy against China's aggressively low prices.”
Journal
Nature Communications
Article Title
Re-evaluation of battery-grade lithium purity toward sustainable batteries
Article Publication Date
8-Feb-2024