image: Scanning confocal microscope image of a single mixed-halide perovskite crystal showing emission from mixed (green) and segregated (red) regions. The central region is exposed to intense light, which causes the halide-ions in this region to mix, generating green (540-570 nm) fluorescence. The red emission (>660 nm) is from phase-segregated perovskite driven by the low-intensity confocal microscope scanning laser. view more
Credit: ARC Centre of Excellence in Exciton Science
Researchers in Australia have resolved a fundamental challenge preventing the wide uptake of next-generation perovskite solar cells.
Metal-halide perovskites, a class of hybrid organic-inorganic materials, provide a cheap, flexible and highly promising pathway for efficient solar photovoltaics, as well as light emissive devices and fast x-ray detectors.
However, since gaining prominence over the last decade, perovskite materials have presented scientists and engineers with several problems precluding their widespread use in commercial applications.
Among these is light-induced phase segregation, in which illumination, such as sunlight, disrupts the carefully arranged composition of elements within mixed-halide perovskites.
This in turn leads to instability in the material's bandgap, interfering with the wavelengths of light absorbed, while reducing charge-carrier conduction and the efficiency of devices.
Now, though, an unlikely solution has been identified.
Members of the ARC Centre of Excellence in Exciton Science have shown that high-intensity light will undo the disruption caused by light at lower intensities, and that this approach can be used to actively control the material's bandgap.
The results have been published in the journal Nature Materials.
Dr Chris Hall, a member of Professor Trevor Smith's team at The University of Melbourne, and Dr Wenxin Mao of Professor Udo Bach's group at Monash University, first noticed the potential to explore this avenue of investigation during a separate experiment.
"It was one of those unusual discoveries that you sometimes hear about in science," Chris said.
"We were performing a measurement, looking for something else, and then we came across this process that at the time seemed quite strange. However, we quickly realised it was an important observation."
They enlisted the help of Dr Stefano Bernardi, a member of Dr Asaph Widmer-Cooper's group at the University of Sydney, who led the computational modelling work to better understand their surprising solution to the issue.
Stefano said: "What we found is that as you increase the excitation intensity, the local strains in the ionic lattice, which were the original cause of segregation, start to merge together. When this happens, the local deformations that drove segregation disappear.
"On a normal sunny day, the intensity is so low that these deformations are still localised. But if you find a way to increase the excitation above a certain threshold, for example by using a solar concentrator, then segregation disappears."
The implications of the findings are significant, with researchers now able to retain the optimal composition of elements within mixed-halide perovskites when they are exposed to light, necessary for its use in solar cells.
"A lot of people have approached this problem by investigating ways of suppressing light-induced disorder, such as looking at different compositions of the material or changing the dimensions of the material," Chris said.
"What we've shown is that you can actually use the material in the state that you want to use it, for a solar cell - all you need to do is focus more light onto it.
"An exciting extension of this work is that the ability to rapidly switch the bandgap with light opens an interesting opportunity to use perovskites in data storage," Wenxin said.
Chris added: "We've done the fundamental work and the next step is to put it into a device."
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Paper details
Light-Induced Reversal of Ion-Segregation in Mixed-Halide Perovskites
DOI: 10.1038/s41563-020-00826-y
Journal: Nature Materials
Authors: Wenxin Mao1,4†, Christopher R. Hall2†, Stefano Bernardi3, 6†, Yi-Bing Cheng4,5, Asaph Widmer-Cooper3, 6*, Trevor A. Smith2*, Udo Bach1,4*
1: Australian Research Council Centre of Excellence in Exciton Science, Department of Chemical Engineering, Monash University, Clayton, Vic 3800, Australia.
2: Australian Research Council Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Melbourne, Vic 3010, Australia.
3: Australian Research Council Centre of Excellence in Exciton Science, School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia.
4: The Australian Centre for Advanced Photovoltaics (ACAP), Monash University, Victoria 3800, Australia.
5: State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei, China.
6: The University of Sydney Nano Institute, University of Sydney, Sydney, NSW 2006, Australia.
Correspondence to:
Udo Bach udo.bach@monash.edu
Trevor Smith trevoras@unimelb.edu.au
Asaph Widmer-Cooper asaph.widmer-cooper@sydney.edu.au.
These authors contributed equally to this work.
More about the ARC Centre of Excellence in Exciton Science:
The Centre of Excellence in Exciton Science is funded by the Australian Research Council to bring together researchers and industry to discover new ways to source and use energy. The Centre is a collaboration between Australian universities and international partners to research better ways to manipulate the way light energy is absorbed, transported and transformed in advanced molecular materials. It works with industry partners to find innovative solutions for renewable energy in solar energy conversion, energy-efficient lighting and displays, security labelling and optical sensor platforms for defence. https://excitonscience.com/
Journal
Nature Materials