Washington, DC-- The matter that makes up distant planets and even-more-distant stars exists under extreme pressure and temperature conditions. This matter includes members of a family of seven elements called the noble gases, some of which--such as helium and neon--are household names. New work from a team of scientists led by Carnegie's Alexander Goncharov used laboratory techniques to mimic stellar and planetary conditions, and observe how noble gases behave under these conditions, in order to better understand the atmospheric and internal chemistry of these celestial objects. Their work is published the week of June 15 by Proceedings of the National Academy of Sciences.
The team used a diamond-anvil cell to bring the noble gases helium, neon, argon, and xenon to more than 100,000 times the pressure of Earth's atmosphere (15-52 gigapascals), and used a laser to heat them to temperatures ranging up to 50,000 degrees Fahrenheit (about 28,000 degrees Kelvin).
The gases are called "noble" due to a kind of chemical aloofness; they normally do not combine, or "react," with other elements. Of particular interest were changes in the gases' ability to conduct electricity as the pressure and temperature changed, because this can provide important information about the ways that the noble gases do actually interact with other materials in the extreme conditions of planetary interiors and stellar atmospheres.
Insulators are materials that are unable to conduct the flow of electrons that make up an electric current. Conductors, or metals, are materials that can maintain an electrical current. Nobel gases are not normally conductive at ambient pressures, but conductivity can be induced under higher pressures.
The research team--which included Carnegie's Stewart McWilliams (the lead author), and Douglas Allen Dalton, as well as Mohammad Mahmood of Howard University and Zuzana Konopkova of Deutsches Elektronen-Synchrotron Photon Science in Hamburg, Germany--found that helium, neon, argon, and xenon transform from visually transparent insulators to visually opaque conductors under varying extreme conditions that mimic the interiors of different stars and planets.
This has several exciting implications for how noble gases behave in the atmospheres and interiors of planets and stars.
For example, it could help solve the mystery of why Saturn emits more heat from its interior than would be expected given its stage of formation. This is tied to the ability, or inability, of the noble gases to be dissolved in the liquid hydrogen present in abundance in the interior of gas giant planets such as Saturn and Jupiter.
In Jupiter and Saturn, helium would be insulating near the surface and turn metal-like at depths close to both planet's cores. The change from insulator to metal occurs under pressure and temperature conditions at which hydrogen--the main constituent of these planets--is also known to be metallic. It is predicted that helium is, in fact, dissolved in hydrogen under these conditions on both planets and, furthermore, that the miscibility--or ability of two substances to mix--of hydrogen-helium mixtures is correlated with this kind of insulator-to-metal transformation.
However, there was an observed difference in the behavior of neon between the laboratory conditions mimicking the two gas giants. The team's results indicate that neon would remain an insulator even in Saturn's core. As such, an ocean-like envelope of undissolved neon could collect deep within the planet and prevent the erosion of Saturn's core compared to its neighbor Jupiter, where core materials, such as iron, would be dissolving into the surrounding liquid hydrogen.
This lack of core erosion could potentially explain why Saturn is giving off so much internal heat compared to its neighbor Jupiter. Erosion of a planet's core, as in Jupiter, leads to planetary cooling as dense matter is raised upward during mixing, converting heat to gravitational potential energy, whereas in Saturn denser material is allowed to collect at the center of the planet, producing hotter conditions. The fact that Saturn gives off a great deal of internal heat has been a longstanding mystery. These findings could provide the key to solving it.
Another implication of the team's findings involves white dwarf stars, which are the collapsed remnants of once-larger stars, having about the mass of our Sun. They are very compact, but have faint luminosities as they give off residual heat. Dense helium is known to exist in the atmospheres of white dwarf stars and may form the surface atmosphere of some of these celestial bodies. The conditions simulated by the team's laser-heated diamond-anvil cell indicate that this stellar helium should be more opaque (and conducting) than previously expected and this opacity could slow the cooling rates of helium-rich white dwarfs, as well as affect their color.
"Our findings provide yet another example of the vast array of applications for extreme pressure research," Goncharov said. "Further research could reveal so much more about what's going on in the interiors of these objects that are too distant for us to observe more directly."
This work was supported by the National Science Foundation Major Research Instrumentation program, the Army Research Office, the Carnegie Institution for Science, the Deep Carbon Observatory Instrumentation grant; the British Council Researcher Links programme; the US Department of Energy NNSA Carnegie/DOE Alliance Center, and the DOE EFRC for Energy Frontier Research in Extreme Environments.
The Carnegie Institution for Science is a private, nonprofit organization headquartered in Washington, D.C., with six research departments throughout the U.S. Since its founding in 1902, the Carnegie Institution has been a pioneering force in basic scientific research. Carnegie scientists are leaders in plant biology, developmental biology, astronomy, materials science, global ecology, and Earth and planetary science.
Proceedings of the National Academy of Sciences