New York, NY--May 6, 2019--Hypersaline brines--water that contains high concentrations of dissolved salts and whose saline levels are higher than ocean water--are a growing environmental concern around the world. Very challenging and costly to treat, they result from water produced during oil and gas production, inland desalination concentrate, landfill leachate (a major problem for municipal solid waste landfills), flue gas desulfurization wastewater from fossil-fuel power plants, and effluent from industrial processes.
If hypersaline brines are improperly managed, they can pollute both surface and groundwater resources. But if there were a simple, inexpensive way to desalinate the brines, vast quantities of water would be available for all kinds of uses, from agriculture to industrial applications, and possibly even for human consumption.
A Columbia Engineering team led by Ngai Yin Yip, assistant professor of earth and environmental engineering, reports that they have developed a radically different desalination approach--"temperature swing solvent extraction (TSSE)"--for hypersaline brines. The study, published online in Environmental Science & Technology Letters, demonstrates that TSSE can desalinate very high-salinity brines, up to seven times the concentration of seawater. This is a good deal more than reverse osmosis, the gold-standard for seawater desalination, and can hold handle approximately twice seawater salt concentrations.
Currently, hypersaline brines are desalinated either by membrane (reverse osmosis) or water evaporation (distillation). Each approach has limitations. Reverse osmosis methods are ineffective for high-saline brines because the pressures applied in reverse osmosis scale with the amount of salt: hypersaline brines require prohibitively high pressurizations. Distillation techniques, which evaporate the brine, are very energy-intensive.
Yip has been working on solvent extraction, a separation method widely employed for chemical engineering processes. The relatively inexpensive, simple, and effective separation technique is used in a wide range of industries, including production of fine organic compounds, purification of natural products, and extraction of valuable metal complexes.
"I thought solvent extraction could be a good alternative desalination approach that is radically different from conventional methods because it is membrane-less and not based on evaporative phase-change," Yip says. "Our results show that TSSE could be a disruptive technology--it's effective, efficient, scalable, and can be sustainably powered."
TSSE utilizes a low-polarity solvent with temperature-dependent water solubility for the selective extraction of water over salt from saline feeds. Because it is membrane-less and not based on evaporation of water, it can sidestep the technical constraints that limit the more traditional methods. Importantly, TSSE is powered by low-grade heat (< 70 C) that is inexpensive and sometimes even free. In the study, TSSE removed up to 98.4% of the salt, which is comparable to reverse osmosis, the gold standard for seawater desalination. The findings also demonstrated high water recovery >50% for the hypersaline brines, also comparable to current seawater desalination operations. But, unlike TSSE, reverse osmosis cannot handle hypersaline brines.
"We think TSSE will be transformational for the water industry," he adds. "It can displace the prevailing practice of costly distillation for desalination of high-salinity brines and tackle higher salinities that RO cannot handle," Yip adds. "This will radically improve the sustainability in the treatment of produced water, inland desalination concentrate, landfill leachate, and other hypersaline streams of emerging importance. We can eliminate the pollution problems from these brines and create cleaner, more useable water for our planet."
Yip's TSSE approach has a clear path to commercialization. The heat input can be sustainably supplied by low-grade thermal sources such as industrial waste heat, shallow-well geothermal, and low-concentration solar collectors. He is now working on further refining how TSSE works as a desalination method so that he can engineer further improvements in performance and test it with real-world samples in the field.
About the Study
The study is titled "Membrane-less and Non-evaporative Desalination of Hypersaline Brines by Temperature Swing Solvent Extraction."
Authors are: Chanhee Boo,† Robert K. Winton,† Kelly M. Conway,† and Ngai Yin Yip*,†,‡
† Department of Earth and Environmental Engineering, Columbia Engineering
‡ Columbia Water Center, Columbia University
The authors declare no financial or other conflicts of interest.
Columbia Engineering, based in New York City, is one of the top engineering schools in the U.S. and one of the oldest in the nation. Also known as The Fu Foundation School of Engineering and Applied Science, the School expands knowledge and advances technology through the pioneering research of its more than 220 faculty, while educating undergraduate and graduate students in a collaborative environment to become leaders informed by a firm foundation in engineering. The School's faculty are at the center of the University's cross-disciplinary research, contributing to the Data Science Institute, Earth Institute, Zuckerman Mind Brain Behavior Institute, Precision Medicine Initiative, and the Columbia Nano Initiative. Guided by its strategic vision, "Columbia Engineering for Humanity," the School aims to translate ideas into innovations that foster a sustainable, healthy, secure, connected, and creative humanity.
Environmental Science & Technology Letters