A team led by the Department of Energy's Oak Ridge National Laboratory used state-of-the-art microscopy to identify a previously undetected feature, about 5 billionths of a meter (nanometers) wide, in a solid electrolyte. The work experimentally verifies the importance of that feature to fast ion transport, and corroborates the observations with theory. The new mechanism the researchers report in Advanced Energy Materials points out a new strategy for the design of highly conductive solid electrolytes.