Insight into the synergistic effect of rare-earth elements on the CMAS corrosion behavior in (RE1/4Tm1/4Yb1/4Lu1/4)2Si2O7 (RE = Gd, Ho and Sc) materials at 1300 °C
Peer-Reviewed Publication
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This study mainly focuses on the RE element synergy mechanisms in disilicates. Three novel multicomponent (RE1/4Tm1/4Yb1/4Lu1/4)2Si2O7 (RE = Gd, Ho and Sc) materials were elaborately designed and subjected to CMAS corrosion at 1300 °C for durations of 1, 4, and 50 h to elucidate the synergistic mechanisms of multicomponent rare-earth elements on CMAS corrosion. Systematical examinations on evolution of reactants and products were conducted to analyze the role of rare-earth cations in CMAS corrosion, and the results reveal that performance divergence in corrosion primarily stems from a mechanistic transition, from dissolution-reprecipitation to intergranular penetration, dictated by rare-earth ionic characteristics. Comparative analysis confirms that an optimal active/inert stoichiometric ratio could simultaneously stimulate the precipitation-induced corrosion mitigation and the intrinsic resistance enhancement, establishing a design framework for multicomponent rare-earth disilicates for anti-CMAS EBC applications.
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