First discovery of two-band superconductivity in intercalated rhombohedral ZrNCl
Shanghai Jiao Tong University Journal CenterPeer-Reviewed Publication
The multiband superconductor offers a unique venue for investigating the interplay between Cooper pairing and inter-band interactions. Here we report the emergence of two-band superconductivity in hybridized superlattice Na (1,3-diaminopropane)ZrNCl. The intercalation of organic molecules and Na ions into the interlayer modulates the electronic structure near the Fermi surface, and promotes the emergence of intrinsic superconductivity with onset transition temperature Tc = 15K. Systematical investigations of upper critical field Hc2 reveals that temperature dependence of Hc2 can be well-described by two-band theory, yielding the out-of-plane and in-plane Hc2 values of 2.9 T and 11.5 T, respectively. Furthermore, analysis of the reversible magnetization data confirms the intrinsic two-band characteristics, which deviate significantly from the predictions of the single-band Ginzburg–Landau(GL)model. Meanwhile, the superconducting state exhibits a two-fold rotational symmetry under in-plane magnetic fields, contrasting with the three-fold symmetric ZrNCl lattice. Angle-dependent Hc2 behavior aligns with the three-dimensional (3D) anisotropic GL model. These findings establish the intercalated rhombohedral ZrNCl as a compelling platform for exploring multiband superconductivity. One-Sentence Summary: Discovery of two-band superconductivity in the intercalated rhombohedral ZrNCl system, which was supported by the upper critical field and reversible magnetization experiments.
- Journal
- Superconductivity