News from China
Updates every hour. Last Updated: 26-Dec-2025 16:11 ET (26-Dec-2025 21:11 GMT/UTC)
BaTiO3 nanoparticle‑induced interfacial electric field optimization in chloride solid electrolytes for 4.8 V all‑solid‑state lithium batteries
Shanghai Jiao Tong University Journal CenterPeer-Reviewed Publication
Chloride-based solid electrolytes are considered promising candidates for next-generation high-energy–density all-solid-state batteries (ASSBs). However, their relatively low oxidative decomposition threshold (~ 4.2 V vs. Li+/Li) constrains their use in ultrahigh-voltage systems (e.g., 4.8 V). In this work, ferroelectric BaTiO3 (BTO) nanoparticles with optimized thickness of ~ 50–100 nm were successfully coated onto Li2.5Y0.5Zr0.5Cl6 (LYZC@5BTO) electrolytes using a time-efficient ball-milling process. The nanoparticle-induced interfacial ionic conduction enhancement mechanism contributed to the preservation of LYZC’s high ionic conductivity, which remained at 1.06 mS cm−1 for LYZC@5BTO. Furthermore, this surface electric field engineering strategy effectively mitigates the voltage-induced self-decomposition of chloride-based solid electrolytes, suppresses parasitic interfacial reactions with single-crystal NCM811 (SCNCM811), and inhibits the irreversible phase transition of SCNCM811. Consequently, the cycling stability of LYZC under high-voltage conditions (4.8 V vs. Li⁺/Li) is significantly improved. Specifically, ASSB cells employing LYZC@5BTO exhibited a superior discharge capacity of 95.4 mAh g−1 over 200 cycles at 1 C, way outperforming cell using pristine LYZC that only shows a capacity of 55.4 mAh g−1. Furthermore, time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy analysis revealed that Metal-O-Cl by-products from cumulative interfacial side reactions accounted for 6% of the surface species initially, rising to 26% after 200 cycles in pristine LYZC. In contrast, LYZC@5BTO limited this increase to only 14%, confirming the effectiveness of BTO in stabilizing the interfacial chemistry. This electric field modulation strategy offers a promising route toward the commercialization of high-voltage solid-state electrolytes and energy-dense ASSBs.
- Journal
- Nano-Micro Letters
Recent advances in the combustion of renewable biofuel diethyl ether: A review
Shanghai Jiao Tong University Journal CenterDiethyl ether (DEE, C4H10O) has emerged as a promising renewable alternative to conventional diesel fuels, offering potential solutions for sustainable energy development. This review systematically examines the fundamental combustion characteristics of DEE, including pyrolysis and oxidation behaviors, kinetic modeling, and actual combustion characteristics. It comprehensively summarized the key research progress and main findings in this field. Research has indicated that DEE demonstrates excellent ignition performance, whether used alone or as an additive, and significantly reduces soot formation during combustion by limiting the discharge of C3-C4 hydrocarbon species. However, a complete mechanistic understanding of DEE combustion still remains limited by the lack of key coupling reaction pathways, which directly restricted the accuracy of the reaction kinetic model. At the actual combustion level in devices, the effects of DEE on engine performance, combustion behavior, and emissions has been investigated. Although a large number of experiments have confirmed that DEE has a significant improvement effect in the above aspects, certain performance degradation phenomena and their internal mechanism still require further elucidation. Based on these insights, this review also analyzes the key challenges facing DEE in practical applications and discusses possible solutions, aiming to build a complete research framework spanning from fundamental studies to engineering application future development.
- Journal
- Frontiers in Energy
On-chip differential mode group delay manipulation based on 3D waveguides
Shanghai Jiao Tong University Journal CenterMode-division multiplexing based on few-mode optical fiber is a promising technology to increase the transmission capacity of optical communication systems, where multi-input multi-output (MIMO) digital signal processing (DSP) is employed to (de)multiplex the signals from different mode channels. Since the group velocity of each mode is different, the signals are separated in the time domain when they reach the receivers. Therefore, it is necessary to compensate for the mode-group-velocity delay of the interval modes to reduce the complexity of the MIMO-DSP algorithm. In this work, we demonstrated an on-chip differential-mode group delay (DMGD) manipulating device based on 3D multilayer cladding waveguides. The proposed device supports compensating the DMGD of about 10.0 ps/m with a device formed with a low refractive index difference. In the meanwhile, the value of DMGD can be greatly improved to be 1878.6 ps/m by forming the device with high refractive index difference material such as thin-film lithium niobate with silicon dioxide cladding. The proposed device provides a feasible design for on-chip DMGD manipulation, which can find various applications in the mode division multiplexing system.
- Journal
- Chip
Key factors influencing success and failure of public-private partnerships in China
Shanghai Jiao Tong University Journal CenterPeer-Reviewed Publication
Abstract
Purpose – This paper studies the determinants for the desirability of the public-private partnership (PPP) mode in infrastructure development.
Design/methodology/approach – The author manually collects data on over 12,000 PPP projects in China, and regard the successful transition and abnormal termination as signals for the mode’s desirability and undesirability, respectively. Then, guided by relevant theories in the literature, the author investigates the impact of various project characteristics on the projects’ successful transition and abnormal termination.
Findings – First, execution-stage projects in industries where government support is indispensable, or where quality improvement is more important than cost reduction, face higher likelihood of abnormal termination. But such negative effects are mitigated if state-owned enterprises (SOEs) participate in the social party. Second, the structure of social party matters. The participation by private firms in the social party increases the termination likelihood, while the decentralization of the social party decreases it. Third, pre-execution projects with government payment or subsidies are more likely to enter into the execution stage.
Practical implications – Regulations on participation by SOEs in PPPs, such as policy [2023 No. 115] announced by State Council, should take industrial heterogeneity into consideration.
Originality/value – Using a large sample, the author empirically tests the seminal PPP-related theoriesin the literature. The author also uncovers some unique stylized facts about PPPs in China, especially the impact of SOE participation in the social party on PPP survival.
- Journal
- China Finance Review International
The efficacy and safety of improved laser ablation in the lung: a pilot study
National Center for Respiratory MedicinePeer-Reviewed Publication
- Journal
- Journal of Thoracic Disease
Tubeless anesthesia with preserved spontaneous breathing: safe and effective in enhanced recovery after thoracoscopic wedge resection of the lung
National Center for Respiratory MedicinePeer-Reviewed Publication
- Journal
- Journal of Thoracic Disease
The hospital length of stay and mortality and its risk and protective factors among patients with acute respiratory distress syndrome receiving extracorporeal membrane oxygenation: a systematic review and meta-analysis
National Center for Respiratory MedicinePeer-Reviewed Publication
- Journal
- Journal of Thoracic Disease
Dosimetric comparison between biaxially rotational dynamic radiation therapy and volumetric modulated arc therapy for locally advanced non-small cell lung cancer
National Center for Respiratory MedicinePeer-Reviewed Publication
- Journal
- Journal of Thoracic Disease
A computed tomography-based lung radiomics nomogram to identify acute exacerbation of chronic obstructive pulmonary disease: a multi-institutional validation study
National Center for Respiratory MedicinePeer-Reviewed Publication
- Journal
- Journal of Thoracic Disease