Enhanced electrode stability over engineering Co-B bonds in Co(OH)2-Ru heterostructure for electrocatalytic water splitting
Peer-Reviewed Publication
Updates every hour. Last Updated: 28-Oct-2026 11:16 ET (28-Oct-2026 15:16 GMT/UTC)
ABSTRACT: Strengthening the stability of metal-oxygen bonds in catalysts is imperative for the advancement of efficient and durable electrocatalytic water splitting. Herein, using a mild boron-reduction strategy, a self-supported electrode with robust Co-B bonds was constructed. The Co-B@Co(OH)2–Ru/NF (Co-B@CRN) electrode demonstrates low overpotentials for alkaline hydrogen evolution reaction (HER, 20 mV) and oxygen evolution reaction (OER, 160 mV) at 10 mA cm⁻2. Furthermore, long-term stability was achieved for over 400 h at 10 mA cm⁻2 and 270 h at 200 mA cm⁻2, respectively. For overall water splitting, the assembled electrolyzer exhibited a low voltage of 1.40 V at 10 mA cm⁻2, with stable operation maintained for over 240 h. Detailed X-ray absorption fine structure (EXAFS) characterization verified the mixed valence state of Co and the Co-B coordination environment. Further electronic analysis indicated strong hybridization between Co d-orbitals and B p-orbitals. The B bonding induced a downward shift in the d-band center at the Co site, thereby significantly suppressing metal leaching during catalysis and stabilizing electronic structure regulation. This research shows that the boron reduction strategy offers an effective dynamic regulation mechanism for the electronic structures and coordination environments of transition metals, enabling a highly efficient and stable overall water splitting process.
As demands for high-quality wound management, health monitoring, and intelligent interaction rise, e-skin—designed to replicate human skin’s flexibility, self-healing ability, and multimodal sensing functions—has steadily emerged as a prominent new research focus. Here, we present a natural biomass-derived multimodal conductive e-skin patch (CCMP) that fabricated by integrating aminated multi-walled carbon nanotubes (MWCNTs-NH2) and dopamine (DA) into carboxymethyl starch (CMS)/carboxymethyl chitosan (CMCS)/polyvinyl alcohol (PVA) matrix through supramolecular interactions assembly. The CCMP demonstrated remarkable electrical conductivity (24.1 S/m), efficient photothermal conversion (with a heating time constant τs = 66.66 s), strong antioxidant activity (>96.53%), effective antibacterial performance, hydrophobicity, electromagnetic shielding capability, as well as high sensitivity to temperature (TCR = −8.58 %/°C), strain, and electrical signals. Furthermore, the CCMP also demonstrated ultra-high swelling properties. Notably, the CCMP presented easy re-shaping and ultra-high swelling capacity (water sorption reached 1374%), promoting the rapid absorption of tissue exudate. Meanwhile, the CCMP can significantly promote wound healing and reduce pro-inflammatory factor levels, achieving an exceptional 99% healing rate within 14 days. We additionally integrate a portable wireless wearable sensing system that can transmit real-time wound status micro-motion and multimodal physiological signals (temperature, stress-strain, respiration, motion, and bioelectric signals) via Bluetooth to computers or mobile devices, thus achieving integrated skin-interfacing wearable bioelectronics and smart wound healing. Overall, this study pioneers a novel approach for wireless wound monitoring system, advancing human-friendly e-skin patch development from single-functional devices to a human-machine-environment intelligent symbiosis system.
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