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Kyoto, Japan -- The stability of the iron atom's nucleus has made it one of the most abundant heavy elements in the universe. When excited, iron atoms emit distinctive fluorescent X-ray lines which can be identified using the Fe Kα emission line, an approximately 6.4 keV fluorescent line produced when an electron transitions from the 2p orbital to the 1s orbital of the atom.
The Fe Kα emission line is widely used as a diagnostic tool for understanding the physical conditions of matter across a variety of astronomical objects. The energy of an emission line depends on the ionization state of iron: the degree to which its electrons have been stripped away. As ionization progresses and electrons are removed, the effective electric attraction between each remaining electron and the atomic nucleus becomes stronger.
From this, one might expect the energy of the Fe Kα emission line to increase as ionization increases. However, theoretical studies have demonstrated that, for iron, there exists a limited range of low ionized states in which the energy of the Fe Kα line sees a slight decrease instead of an increase. This happens because during the removal of electrons from the 3d orbital, the repulsion between electrons within the 3d shell is reduced, and the 3d orbital contracts toward the nucleus. While the Fe Kα emission line corresponds to the 2p → 1s transition, the Fe Kβ line corresponds to the 3p → 1s transition, and this line increases almost uniformly with increasing ionization.