World’s smallest molecular machine: reversible sliding motion in ammonium-linked ferrocene
Peer-Reviewed Publication
Updates every hour. Last Updated: 4-May-2025 13:09 ET (4-May-2025 17:09 GMT/UTC)
Ferrocene is a key molecule for developing molecular machines. However, it readily decomposes on the surface of flat noble metal substrates, marking a significant challenge. Now, for the first time, researchers stabilized ferrocene by linking it with ammonium salts and trapping them in a molecular film made up of cyclic crown ether molecules. The ammonium-linked molecule performs reversible lateral sliding motion upon the application of electrical voltage, representing the world's smallest molecular machine.
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