Polyphenol‑gated composite electrolytes with enhanced cross‑phase lithium‑ion transport for solid‑state lithium batteries
Peer-Reviewed Publication
Updates every hour. Last Updated: 21-Apr-2026 10:17 ET (21-Apr-2026 14:17 GMT/UTC)
Solid-state lithium (Li) batteries offer high-energy density and operational safety but face sluggish Li+ transport in polymer/ceramic composite solid-state electrolytes. Herein, we propose a bioinspired polyphenol-gated interfacial engineering that mimics ion-selective protein channels to enhance Li+-selective transport across the polymer–ceramic interface. Polyphenols such as polydopamine, poly-tannic acid, and poly-gallic acid chemically couple La0.56Li0.33TiO3 ceramic nanofibers and glycidyl polyether matrix. Within this interface, carbonyl groups selectively coordinate Li⁺ and facilitate directional migration. On the other hand, hydroxyl and amino groups immobilize anions via hydrogen bonding. This chemical gating nearly doubles interfacial Li+ concentration and boosts transference number to 0.68. The corresponding Li||LiFePO4 battery exhibits stable cycling over 600 cycles with 85.5% capacity retention at 1 C, while the pouch cell delivers reliable operation under mechanical stress caused by bending and puncturing. This work demonstrates that polyphenol-gated interfaces are essential for promoting selective and efficient cross-phase Li⁺ transport for high-performance solid-state lithium-metal batteries.
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