25-Mar-2025
New study uncovers key pathways in hydronium and hydroxide ion neutralization
The Hebrew University of JerusalemPeer-Reviewed Publication
A new study provides fresh insight into traditional acid-base chemistry by revealing that the mutual neutralization of isolated hydronium (H₃O⁺) and hydroxide (OH⁻) ions is driven by electron transfer rather than the proton transfer that is expected in bulk liquid water. Using deuterated water ions and advanced 3D coincidence imaging of the neutral products, researchers found two electron-transfer mechanisms that produce hydroxyl radicals (OH), which are crucial in atmospheric chemistry. These findings reshape our understanding of fundamental reaction dynamics and help explain the surprising finding of high OH and H2O2 concentrations at water microdroplet surfaces. This discovery is significant because OH radicals play a key role in air quality, climate science, and even biochemical processes in the human body. By uncovering unexpected chemical reaction pathways, the study could influence future research on planetary and interstellar medium chemistry, as well as pollution control and medical applications.
- Journal
- Nature Chemistry
- Funder
- Swedish National Infrastructure, DESIREE, Swedish Research Council, Knut and Alice Wallenberg Foundation, Air Force Office of Scientific Research, COST, ISF, Minerva Center