Operando X-ray tomography reveals silicon–electrolyte interface dynamics in all-solid-state batteries
Peer-Reviewed Publication
Updates every hour. Last Updated: 20-Dec-2025 14:11 ET (20-Dec-2025 19:11 GMT/UTC)
Silicon anodes can greatly boost the energy density of all-solid-state batteries, but their large volume changes often cause contact loss with solid electrolytes. Using operando synchrotron X-ray micro- and nano-computed tomography, researchers at Ritsumeikan University directly visualized the 3D evolution of the silicon–electrolyte interface during charge and discharge cycling. They found that even as silicon expands and shrinks, the thin, solid-electrolyte layers remain adhered, preserving partial ion pathways and enabling stable operation.
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