23-Oct-2025
3D polymer design powers record-high zinc–organic battery performance
KeAi Communications Co., Ltd.Organic cathodes have long been sought after for safe, sustainable, and recyclable energy storage, yet their development has been hampered by solubility, low voltage, and poor conductivity. In this study, researchers report a hexaazatriphenylene-based polymer with a three-dimensional (3D) framework that successfully addresses these challenges. The material exhibits remarkable insolubility, strong electronic delocalization, and accessible redox sites, resulting in a zinc–organic battery with an impressive initial discharge voltage of 1.32 V and an extraordinary lifespan of more than 40,000 cycles with over 93% capacity retention. This work provides a new molecular design strategy for creating high-voltage, ultrastable organic batteries.
- Journal
- eScience
- Funder
- National Natural Science Foundation of China, Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications