Flying robots unlock new horizons in construction
Peer-Reviewed Publication
Updates every hour. Last Updated: 24-May-2025 11:09 ET (24-May-2025 15:09 GMT/UTC)
An international team led by researchers from Empa and EPFL has explored how in future aerial robots could process construction materials precisely in the air – an approach with great potential for difficult-to-access locations or work at great heights. The flying robots are not intended to replace existing systems on the ground, but rather to complement them in a targeted manner for repairs or in disaster areas, for instance.
Two-dimensional porphyrin-based COFs show great promise for photocatalytic CO2 reduction, yet their π-π stacking often impedes active site exposure and charge transfer. Researchers developed a series of porphyrin COFs with tunably twisted linkers. The N-N-linked twisted unit in NN-Por-COF creates a remarkably undulating layered structure that enhances mass transport and exposes more active sites, while simultaneously modulating the electronic structure of cobalt-porphyrin to reduce reaction barriers. This dual structural and electronic optimization yields outstanding photocatalytic performance, achieving CO production rates of 22.38 and 3.02 mmol g−1 h−1 under pure and 10% CO2, respectively, surpassing most porphyrin-based photocatalysts.
Cationic Ir(III) complex bound to synthetic saponite was used as a donor for TTA-UC(Triplet-triplet annihilation up-conversion)with 9,10-diphenylanthracne.
High quantum yield of TTA-UC was attained due to the hybridization with organically modified synthetic saponite in R-limonene.
Since R-limonene is a natural product belonging to a green solvent, the present finding may promise the possible utility of clay minerals for TTA-UC in green solvents.