Engineering Porous Carbon

Electromagnetic-wave pollution and electromagnetic interference are growing concerns alongside the expansion of 5G and 6G communications, radar systems, the Internet of Things, and high-speed electronics. Researchers from Shenyang Aerospace University, AVIC Shenyang Aircraft Co. Ltd., Shenyang Agricultural University, and the Institute of Strength Physics and Materials Science SB RAS developed lightweight carbon aerogels designed to address both microwave absorption and heat management.

The materials were prepared from chitosan and chitin nanofibrils using directional freezing, carbonization, solvothermal deposition, and a second carbonization step. Adjusting the relative content of the rigid chitin nanofibrils altered the pore architecture from vertically layered structures to aligned, straight-through polygonal channels. Rational pore-structure control allowed the researchers to tune electrical conductivity, dielectric response, impedance matching, and electromagnetic-energy dissipation.

CoNi Components Add Magnetic Loss

CoNi-based metal–organic frameworks were deposited in situ onto the carbon aerogel skeleton and converted into CoNi@C components during carbonization. Microscopy, X-ray diffraction, spectroscopy, and elemental mapping confirmed the porous carbon framework, graphitized carbon, nitrogen-containing structures, and dispersed CoNi alloy nanocrystals.

Tracking a Missing Kinetic Dimension

Dissolved black carbon (DBC) is a mobile, redox-active fraction of carbon formed during biomass combustion and pyrolysis. Although electron-donating and electron-accepting capacities describe how much charge a material can exchange, they do not indicate how quickly that exchange occurs. Work led by Yufei Wu, Peng Zhang, Zhaofeng Chang, and Bo Pan at Kunming University of Science & Technology quantified the apparent heterogeneous electron-transfer rate constant, k₀, as a kinetic measure of DBC reactivity.

Comparing Carbon Sources and Temperatures

The team examined 10 DBC samples produced from rice straw and sawdust at pyrolysis temperatures of 200–600 °C. Cyclic voltammetry and differential pulse voltammetry were conducted with a three-electrode system, while particle-size analysis and mediated electrochemical measurements characterized diffusion and electron-exchange properties. Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS) was used to resolve molecular formulas and assign compound classes. Microbial electrochemical systems containing Shewanella oneidensis MR-1 were used to assess how DBC affected extracellular electron transfer.

A study carried out by the EHU-University of the Basque Country concludes that a more sustainable green hydrogen economy requires a combination of technological improvements and policies that guarantee environmental benefits, economic competitiveness and social responsibility. After analysing various configurations of H₂ production locations and global LOHC-based transport routes, the team concludes that there is no perfect scenario. However, the results show that LOHC technology has significant potential to play a key role in the global green hydrogen trade in the near future.

Binghamton University, State University of New York will receive half a million dollars from New York state for new instrumentation that will advance our understanding of dementia and neurodegenerative diseases more generally.