A new role for catalyst supports in ammonia synthesis
Peer-Reviewed Publication
Updates every hour. Last Updated: 9-Jun-2026 10:15 ET (9-Jun-2026 14:15 GMT/UTC)
Ammonia is a vital chemical feedstock and a promising hydrogen carrier. Through the integration of in situ electron microscopy, spectroscopy, and theoretical calculations, the research team identified that during the ammonia synthesis process, oxygen defects on the surface of the catalyst support can store and transfer active nitrogen species, thereby generating surface nitrogen spillover. This effect accelerates nitrogen activation and enhances ammonia yield. This study elucidates a novel mechanism underlying the promotion of ammonia formation by the support in the Haber–Bosch process, providing new perspectives for the design of higher-efficiency ammonia synthesis catalysts.
Researchers have developed a molecular design strategy to stabilize the delicate interface in inverted perovskite solar cells. By enforcing multidimensional spatial confinement in a custom-designed self-assembled monolayer (MeO-PABDCB), the team created a robust “molecular lock” that boosts the power conversion efficiency of inverted perovskite solar cells to 26.54% while maintaining exceptional durability under continuous operation and thermal cycling (−40 to 85 °C).
Lithium metal batteries promise dramatically higher energy density than today's lithium-ion technology, but their practical use has been limited by unstable interfaces and dangerous lithium dendrite growth. In this study, researchers developed a two-dimensional polymeric metal phthalocyanine layer that actively regulates anion movement and lithium-ion transport at the electrode–electrolyte interface. By guiding electrolyte anions toward the electrode surface and simultaneously accelerating lithium-ion conduction, the engineered layer promotes the formation of dense, lithium fluoride–rich interphases that stabilize lithium deposition. This molecularly designed interface significantly improves cycling stability, Coulombic efficiency, and safety under demanding operating conditions, offering a new strategy to unlock the long-term reliability of lithium metal and anode-free batteries.