Tech & Engineering
Updates every hour. Last Updated: 26-Dec-2025 18:11 ET (26-Dec-2025 23:11 GMT/UTC)
In situ generated sulfate-facilitated efficient nitrate electrosynthesis on 2D PdS2 with unique imitating growth feature
Shanghai Jiao Tong University Journal CenterPeer-Reviewed Publication
As a green sustainable alternative technology, synthesizing nitrate by electrocatalytic nitrogen oxidation reaction (NOR) can replace the traditional energy-intensive Ostwald process. But low nitrogen fixation yields and poor selectivity due to the high bond energy of the N≡N bond and competition from the oxygen evolution reaction in the electrolyte restrict its application. On the other hand, two-dimensional (2D) PdS2 as a member in the family of group-10 novel transition metal dichalcogenides (NTMDs) presents the interesting optical and electronic properties due to its novel folded pentagonal structure, but few researches involve to its fabrication and application. Herein, unique imitating growth feature for PdS2 on different 2D substrates has been firstly discovered for constructing 2D/2D heterostructures by interface engineering. Due to the different exposed chemical groups on the substrates, PdS2 grows as the imitation to the morphologies of the substrates and presents different thickness, size, shape and the degree of oxidation, resulting in the significant difference in the NOR activity and stability of the obtained composite catalysts. Especially, the thin and small PdS2 nanoplates with more defects can be obtained by decorating poly(1-vinyl-3-ethylimidazolium bromide) on the 2D substrate, easily oxidized during the preparation process, resulting in the in situ generation of SO42−, which plays a crucial role in reducing the activation energy of the NOR process, leading to improved efficiency for nitrate production, verified by theoretical calculation. This research provides valuable insights for the development of novel electrocatalysts based on NTMDs for NOR and highlights the importance of interface engineering in enhancing catalytic performance.
- Journal
- Nano-Micro Letters
Land use severely reduces global carbon in plants and soils
Ludwig-Maximilians-Universität MünchenPeer-Reviewed Publication
A new LMU study shows the extent to which human influence is altering natural land carbon stocks.
- Journal
- One Earth
A novel technology to control crystallinity of pore walls
Waseda UniversityPeer-Reviewed Publication
Nanoporous metal oxides have a wide variety of applications, such as catalysts, electrodes, energy materials, sensors, and biomaterials. Recently, a team of researchers has demonstrated a novel synthesis method for their efficient and desirable preparation. Specifically, they prepared difficult-to-prepare quasi-single-crystalline inverse opal α-Fe2O3, demonstrating that crystal growth occurs in nanospace due to volatilization and oxidation of metal chlorides. This technology is expected to further the development of catalytic and energy conversion materials for carbon neutrality.
- Journal
- Chemistry of Materials
New study reveals the gene responsible for diverse color patterns in African violet flower
Kindai UniversityPeer-Reviewed Publication
Until recently, the color variations observed in the petals of Saintpaulia were attributed to periclinal chimera or the influence of genetically distinct cell layers. Now, a new study by researchers from Japan has identified a single gene called SiMYB2 that regulates petal colors in Saintpaulia by producing two distinct mRNA transcripts. This study lays the foundation for future horticulture-related research and can aid the deliberate breeding of patterned flowers.
- Journal
- New Phytologist
Scientists develop new method to create novel layered inorganic materials
Chinese Academy of Sciences HeadquartersPeer-Reviewed Publication
- Journal
- Nature Synthesis
A potential ‘green’ alternative to formaldehyde and PFAS in fabric finishing
American Chemical SocietyReports and Proceedings
Finishing techniques used to make cotton fabric smooth, water-resistant and less prone to wrinkling can contain formaldehyde or PFAS and be detrimental to the environment and the wearer. Now, researchers at North Carolina State University propose a method for using cottonseed oil as a greener and safer alternative to formaldehyde and PFAS when finishing cotton fabrics to make them more water-resistant. They will present their results at ACS Fall 2025.
- Meeting
- ACS Fall 2025