Stereoisomeric engineering for critical balance of solvation and adsorption capability
Peer-Reviewed Publication
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Pyrovanadates are deemed as an ideal class of potential Calcium ion storage hosts, owing to abundant confined species. However, the higher Coulombic hinderance brings about more sluggish diffusion kinetics of charge carriers. Therefore, an allelic reconfiguration is proposed for the activity-limited zinc sites, and a novel solid-solution phase copper/zinc pyrovanadate for calcium-ion host is prepared. Combining theoretical calculations with experiments, the feasibility of the solid solution phase host for high-performance reversible calcium-ion storage is clarified.
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