17-Nov-2025
Visualization of exciton diffusion in a copper phthalocyanine single nanofiber by femtosecond single-particle spectroscopy
Ehime UniversityPeer-Reviewed Publication
A research team led by Associate Professor Yukihide Ishibashi at the Graduate School of Science and Engineering, Ehime University, has successfully achieved the direct observation of exciton diffusion processes within individual copper phthalocyanine(CuPc)nanofibers using a custom-built femtosecond microspectroscopy technique, which enables clarification of exciton dynamics in mesoscopic materials. Previously, only ensemble-averaged information(e.g., CuPc thin films)was available for exciton diffusion coefficients and diffusion lengths. By measuring these parameters for single nanofibers, the team revealed that the diffusion coefficient of η-phase CuPc nanofibers is about three times higher than that of β-phase ones. This enhancement arises from the larger molecular tilt angle and stronger π–π overlap in the η-phase, which promote intermolecular excitonic interactions. Moreover, the diffusion coefficient was found to decrease with increasing fiber length, indicating a “size effect” in exciton hoopping. This study not only deepens the understanding of optical properties in organic molecular crystals but also provides important insights for improving the efficiency of organic photovoltaic and photoenergy-conversion devices. The findings were published online in The Journal of Physical Chemistry Letters by the American Chemical Society on October 31, 2025.
- Journal
- The Journal of Physical Chemistry Letters
- Funder
- Japan Society for the Promotion of Science