Turning step-growth into chain-growth with click polymerization
Peer-Reviewed Publication
Updates every hour. Last Updated: 16-Jul-2025 06:11 ET (16-Jul-2025 10:11 GMT/UTC)
A controlled/“living” click polymerization method developed by researchers at Institute of Science Tokyo and Nagoya University enables precise chain-growth of AB-type monomers—traditionally limited to step-growth processes—by leveraging copper-catalyzed azide–alkyne cycloaddition. The approach achieves well-defined polymers with narrow dispersity and enables the bidirectional synthesis of ABA-type block copolymers, offering a powerful new strategy for constructing functional macromolecular architectures from a wide range of monomers.
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Indium gallium zinc oxide (IGZO)-based displays suffer from instability caused by atomic-scale defects. Now, a new study provides the first insights into these instabilities in single-crystal IGZO. Researchers grew high-quality IGZO single crystals and uncovered how oxygen vacancies and structural disorder create unwanted electronic states—details that were unclear in previous studies using amorphous IGZO samples. These findings could guide the development of more stable and longer-lasting displays for smartphones, televisions, and other devices.
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