A dynamic molecular sunscreen for perovskite solar cells
Peer-Reviewed Publication
Updates every hour. Last Updated: 4-Jun-2026 06:16 ET (4-Jun-2026 10:16 GMT/UTC)
Quasi-solid-state electrolytes (QSEs) are critical for ultrafast-charging yet high-safety sodium metal batteries (SMBs), yet their implementation is hindered by sluggish Na+ transport in bulk and at interfaces. Here, we propose dual interlocked mediator engineering that transcends conventional independent approaches by coupling cationic Sn2+ salt with anionic difluoro(oxalato)borate (DFOB⁻) salts to simultaneously regulating bulk ion transport and bilateral interface chemistry. During QSE preparation, Sn2+ initiates in situ cationic polymerization, while DFOB⁻ acts as a retarding agent to suppress runaway polymerization. The first interlocking effect in the Sn-FB QSE bulk builds a uniform network, enabling near-unity Na+ transference number (0.94) and robust puncture strength (8.5 kPa). During cell operation, Sn2+ is reduced to form a hybrid NaSn alloy-based solid-electrolyte interphase, while DFOB⁻ oxidizes to generate a robust yet thin cathode–electrolyte interphase, respectively. This second interlocking effect creates adaptable bilateral interphases that facilitate Na+ diffusion and mitigate interfacial degradation. As a result, the symmetric cells exhibit 6000 h stability, and full cells retain 80.1 mAh g–1 at an ultrafast-charging rate of 15C and retain 90% capacity at 3C over 2000 cycles. Furthermore, high-mass-loading full cells and pressure-free pouch cells are demonstrated, underscoring the potential of dual interlocked mediator engineering for practical SMBs.
Chiral objects can behave differently depending on their handedness. However, existing methods cannot reveal how chirality varies across a material. Researchers from Chiba University developed a terahertz imaging technique that maps right- and left-handed chirality using spiral-shaped light. The researchers visualized different chiral regions on a moiré-type metasurface with a resolution of about 100 μm, marking the first direct observation of spatial chirality distributions within a material.