Defect-tuned layered double hydroxides open new path for clean energy catalysts
KeAi Communications Co., Ltd.Layered double hydroxides (LDHs) are emerging as promising electrocatalysts for the oxygen evolution reaction (OER), a key barrier in clean hydrogen production. However, their catalytic performance has long been restricted by limited active sites, sluggish electron transfer, and structural instability under operational conditions. A new review summarizes how electronic defect engineering, including vacancy creation, heteroatom doping, single-atom incorporation and lattice modulation, which reconfigures electron distribution, enhances active site exposure, accelerates reaction kinetics, and strengthens catalytic durability. The work highlights strategies that effectively lower OER overpotential and improve stability by tuning LDH atomic coordination environments, providing a unified framework for the design of next-generation high-performance water-splitting catalysts.
- Journal
- eScience
- Funder
- National Natural Science Foundation of China, China Postdoctoral Science Foundation, Natural Science Foundation Project for Outstanding Youth of Henan Province, Nuclear Material Technology Innovation Fund for National Defense Technology Industry, Science and Technology Department of Henan Province