Neutron diffraction unveils the 'relay' of hardening mechanisms in next-gen superalloys
Peer-Reviewed Publication
Updates every hour. Last Updated: 9-Jan-2026 17:11 ET (9-Jan-2026 22:11 GMT/UTC)
Nickel-cobalt (Ni-Co)-based superalloys are leading candidates for advanced turbine disks; however, their strength relies heavily on how dislocations interact with nanoscale γ′ precipitates during deformation. In a new study, researchers combined in-situ neutron diffraction tensile testing with line-profile analysis and electron microscopy to monitor the alloy’s internal response in real time. They discovered a sequential transition in strengthening mechanisms—from γ′ shearing to Orowan looping—accompanied by interphase load transfer from γ to γ′. This study links these microstructural events to changes in dislocation character and configuration, driving the alloy’s characteristic three-stage work-hardening behavior.
TiNb2O7 represents an up-and-coming anode material for fast-charging lithium-ion batteries, but its practicalities are severely impeded by slow transfer rates of ionic and electronic especially at the low-temperature conditions. Herein, we introduce crystallographic engineering to enhance structure stability and promote Li+ diffusion kinetics of TiNb2O7 (TNO). The density functional theory computation reveals that Ti4+ is replaced by Sb5+ and Nb5+ in crystal lattices, which can reduce the Li+ diffusion impediment and improve electronic conductivity. Synchrotron radiation X-ray 3D nano-computed tomography and in situ X-ray diffraction measurement confirm the introduction of Sb/Nb alleviates volume expansion during lithiation and delithiation processes, contributing to enhancing structure stability. Extended X-ray absorption fine structure spectra results verify that crystallographic engineering also increases short Nb-O bond length in TNO-Sb/Nb. Accordingly, the TNO-Sb/Nb anode delivers an outstanding capacity retention rate of 89.8% at 10 C after 700 cycles and excellent rate performance (140.4 mAh g−1 at 20 C). Even at −30 °C, TNO-Sb/Nb anode delivers a capacity of 102.6 mAh g−1 with little capacity degeneration for 500 cycles. This work provides guidance for the design of fast-charging batteries at low-temperature condition.