Novel "point-to-point adsorption" technique enables high-performance nano-floating-gate memory devices
Peer-Reviewed Publication
Updates every hour. Last Updated: 1-Nov-2026 22:15 ET (2-Nov-2026 03:15 GMT/UTC)
We have developed a facile dip-coating method for fabricating ordered two-dimensional (2D) self-assembled block copolymer (BCP) micelle templates on substrates. Through point-to-point adsorption on these micelle templates, 2D non-close-packed, short-range ordered gold nanoparticle (AuNP) arrays were successfully obtained. The study elucidates the governing principles of critical processing parameters: the effects of withdrawal speed and micelle concentration on template morphology, as well as the influence of nanoparticle size and micelle corona thickness on the electrostatic adsorption process, thereby enabling the controllable fabrication of large-area 2D non-close-packed nanoparticle arrays. When employed as nanoscale floating gates in non-volatile memory devices, these BCP@AuNP composite arrays demonstrate superior performance—specifically, the incorporation of AuNPs broadens the memory window and enhances device operational stability compared to pure BCP micelle template layers. This strategy offers distinct advantages including operational simplicity, high efficiency, broad applicability, and cost-effectiveness, without requiring additional pre- or post-treatment steps. The entire process demonstrates substantial potential for industrial-scale fabrication of controllable 2D non-close-packed nanoparticle arrays.
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